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Insight into the promotion mechanism of activated carbon on the monolithic honeycomb red mud catalyst

《环境科学与工程前沿(英文)》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1337-7

摘要:

• Activated carbon was proposed to be an efficient accelerant for molded red mud catalyst.

关键词: NOx     Selective catalytic reduction     Iron-based catalyst     Red mud     Monolithic catalyst     Activated carbon    

Efficient promotion of methane hydrate formation and elimination of foam generation using fluorinated

Quan CAO, Dongyan XU, Huanfei XU, Shengjun LUO, Rongbo GUO

《能源前沿(英文)》 2020年 第14卷 第3期   页码 443-451 doi: 10.1007/s11708-020-0683-2

摘要: Methane hydrate preparation is an effective method to store and transport methane. In promoters to facilitate methane hydrate formation, homogeneous surfactant solutions, sodium dodecyl sulfate (SDS) in particular, are more favorable than heterogeneous particles, thanks to their faster reaction rate, more storage capacity, and higher stability. Foaming, however, could not be avoided during hydrate dissociation with the presence of SDS. This paper investigated the ability of five fluorinated surfactants: potassium perfluorobutane sulfonate (PBS), potassium perfluorohexyl sulfonate (PHS), potassium perfluorooctane sulfonate (POS), ammonium perfluorooctane sulfonate (AOS), and tetraethylammonium perfluorooctyl sulfonate (TOS) to promote methane hydrate formation. It was found that both PBS and PHS achieve a storage capacity of 150 ( , the volume of methane that can be stored by one volume of water) within 30 min, more than that of SDS. Cationic ions and the carbon chain length were then discussed on their effects during the formation. It was concluded that PBS, PHS, and POS produced no foam during hydrate dissociation, making them promising promoters in large-scale application.

关键词: methane hydrate     fluorinated surfactants     homogeneous promoter     foam elimination     stability    

并行推进、融合发展——新一代智能制造技术路线

古依莎娜,董景辰,臧冀原,杨晓迎

《中国工程科学》 2018年 第20卷 第4期   页码 19-22 doi: 10.15302/J-SSCAE-2018.04.004

摘要:

本文通过研究西方发达国家发展智能制造的历程以及我国智能制造发展现状,提出中国发展智能制造不能走西方“串联式”发展道路,必须采取“并行推进、融合发展”的技术路线,推进“数字化制造、数字化网络化制造、数字化网络化智能化制造”三个范式同步发展,在大力推广、应用和普及数字化网络化制造的同时,加快新一代智能制造的探索、研究,引领和推进中国制造业的转型升级、跨越发展。

关键词: 并行推进     融合发展     新一代智能制造    

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

《化学科学与工程前沿(英文)》 2021年 第15卷 第6期   页码 1561-1571 doi: 10.1007/s11705-021-2089-z

摘要: It is of broad interest to develop emerging photocatalysts with excellent light-harvesting capacity and high charge carrier separation efficiency for visible light photocatalytic hydrogen evolution reaction. However, achieving satisfying hydrogen evolution efficiency under noble metal-free conditions remains challenging. In this study, we demonstrate the fabrication of three-dimensionally ordered macroporous SrTiO3 decorated with ZnxCd1−xS nanoparticles for hydrogen production under visible light irradiation (λ>420 nm). Synergetic enhancement of photocatalytic activity is achieved by the slow photon effect and improved separation efficiency of photogenerated charge carriers. The obtained composites could afford very high hydrogen production efficiencies up to 19.67 mmol·g−1·h−1, with an apparent quantum efficiency of 35.9% at 420 nm, which is 4.2 and 23.9 times higher than those of pure Zn0.5Cd0.5S (4.67 mmol·g−1·h−1) and CdS (0.82 mmol·g−1·h−1), respectively. In particular, under Pt-free conditions, an attractive hydrogen production rate (3.23 mmol·g−1·h−1) was achieved, providing a low-cost and high-efficiency strategy to produce hydrogen from water splitting. Moreover, the composites showed excellent stability, and no obvious loss in activity was observed after five cycling tests.

关键词: three-dimensionally ordered macroporous SrTiO3     ZnxCd1–xS     visible light     hydrogen production     promotion mechanism    

奉献清洁电力,推进能源革命

顾大钊

《工程(英文)》 2020年 第6卷 第12期   页码 1331-1332 doi: 10.1016/j.eng.2020.10.005

Air pollutant control and strategy in coal-fired power industry for promotion of China’s emission reduction

Weiliang WANG, Bo LI, Xuan YAO, Junfu LYU, Weidou NI

《能源前沿(英文)》 2019年 第13卷 第2期   页码 307-316 doi: 10.1007/s11708-019-0620-4

摘要: Coal-fired power industry has always been the major power source in China. As coal-fired power industry consumes around a half of China’s coal production, it is always thought to be a big air pollutant emission source. As more and more strict legislations in coal-fired power industry have been issued by the government, the emission performance in coal-fired power industry has been drastically reduced recently. Based on a brief review of the development of emission control in China’s coal-fired power industry, the affecting mechanism among the development of installed capacities of emission control device, pollutant emission, and emission performances in coal-fired power industry is studied. According to a systematic study on the development of emissions of classified categories, the role of coal-fired power industry as a pollutant source is reevaluated. It is found that, coal-fired power industry has contributed the most to China’s emission reduction, and the barycenter of air pollutant emission has been transformed to other high energy consumption industries, like heat, iron/steel, and cement. Then some development strategies are suggested, such as maintaining the current emission standard in coal-fired power industry; expending the coal-fired power emission standards to categories of heat generation and supply, nonmetallic mineral production and ferrous metals smelting and processing; and controlling other heavy metal by consulting the method of Hg control.

关键词: coal-fired power industry     energy intensive industries     pollutant emission control     NOx     SO2     soot    

Health: a dream from reality to the future

null

《医学前沿(英文)》 2016年 第10卷 第2期   页码 233-235 doi: 10.1007/s11684-016-0444-0

摘要:

This paper argues that health is a realistic productive force that may enhance the index of happiness. As the basis of all developments and the source of a person’s and his/her family’s happiness, health requires not only primary and secondary prevention, but also policy prevention, that is to say, grade-zero prevention. Therefore, people should pay more attention to Health in All Policies. As a new preventive strategy, the policy prevention will help improve people’s health significantly and promote the concepts of “Healthy China” and “the Chinese Dream” or “the World Dream” to realize a dream from reality to the future.

关键词: health promotion     primary and secondary prevention     policy prevention     infectious disease     non-communicable disease    

Promotion of transition metal oxides on the NH

Weiman Li, Haidi Liu, Yunfa Chen

《环境科学与工程前沿(英文)》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0914-x

摘要: Manganese and chromium oxides promote the NH -SCR activity of Zr-Ce mixed oxide. Cr-Zr-Ce mixed oxide exhibited>80% NO conversion at a wide temperature window. More acid sites and higher reducibility may responsible for the high SCR ability. Chromium oxide and manganese oxide promoted ZrO -CeO catalysts were prepared by a homogeneous precipitation method for the selective catalytic reduction of NO with NH . A series of characterization including X-ray diffraction (XRD), high-resolution transmission electron microscope (HR-TEM), Brunauer–Emmett–Teller (BET) surface area analysis, H temperature-programmed reduction (H -TPR), and X-ray photoelectron spectroscopy (XPS) were used to evaluate the influence of the physicochemical properties on NH -SCR activity. Cr-Zr-Ce and Mn-Zr-Ce catalysts are much more active than ZrO -CeO binary oxide for the low temperature NH -SCR, mainly because of the high specific surface area, more surface oxygen species, improved reducibility derived from synergistic effect among different elements. Mn-Zr-Ce catalyst exhibited high tolerance to SO and H O. Cr-Zr-Ce mixed oxide exhibited>80% NO conversion at a wide temperature window of 100°C–300°C. DRIFT studies showed that the addition of Cr is beneficial to the formation of Bronsted acid sites and prevents the formation of stable nitrate species because of the presence of Cr . The present mixed oxide can be a candidate for the low temperature abatement of NO .

关键词: NH3-selective catalytic reduction     NOx     Low temperature     Cr-Zr-Ce    

创新的不可预见性及其引发的思考

杨显万,高筱梅

《中国工程科学》 2007年 第9卷 第4期   页码 18-24

摘要:

讨论了创新的不可预见性与可预见性,并就与创新有关的问题及现象做了分析并提出了促进创新的 建议。

关键词: 创新     不可预见的创新     促进创新的建议    

船舶配套业发展研究

汤敏,邱晓峰,胡发国,陈琛

《中国工程科学》 2016年 第18卷 第2期   页码 72-75 doi: 10.15302/J-SSCAE-2016.02.008

摘要:

推进船舶配套自主化,对完善我国船舶工业体系,真正发挥船舶工业对国民经济的带动作用具有重要的意义。本文结合国外造船强国配套业的发展,分析了我国船舶配套业的现状及存在的问题,对推进我国船舶配套自主化提出若干建议。

关键词: 船舶配套业     自主化     推进    

Theory and method of mechanism system design

Huijun ZOU, Qinghua LIANG, Qing ZHANG

《机械工程前沿(英文)》 2010年 第5卷 第4期   页码 399-411 doi: 10.1007/s11465-010-0116-8

摘要: Conceptual design is the most critical and creative phase of design. Recently, increasing attention has been directed to supporting conceptual-level computer aided creative design and its theories and methodologies. Specifically, for conceptual design of mechanical products, this paper presents a novel function solving model for mechanical product design and highlights the importance of systematic synthesis to achieve creative design. Then it builds a framework as a function-effect-process-action- mechanisms (FEPAM) mapping process, which enables creative design on the basis of conceiving different action schemes. After that, several key points are elaborated including 1) representing and decomposition methods of functions and motion behaviors; 2) action scheme representing method based on network plan techniques; and 3) variation and creation methods based on action scheme transformations.

关键词: mechanism system creative design     process model     function solving model     process action procedure     mechanisms knowledge base     principle of mechanism system composition    

Formation mechanism and modeling of surface waviness in incremental sheet forming

《机械工程前沿(英文)》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0679-1

摘要: Improving and controlling surface quality has always been a challenge for incremental sheet forming (ISF), whereas the generation mechanism of waviness surface is still unknown, which impedes the widely application of ISF in the industrial field. In this paper, the formation mechanism and the prediction of waviness are both investigated through experiments, numerical simulation, and theoretical analysis. Based on a verified finite element model, the waviness topography is predicted numerically for the first time, and its generation is attributed to the residual bending deformation through deformation history analysis. For more efficient engineering application, a theoretical model for waviness height is proposed based on the generation mechanism, using a modified strain function considering deformation modes. This work is favorable for the perfection of formation mechanism and control of surface quality in ISF.

关键词: surface waviness     incremental sheet forming     numerical simulation     formation mechanism     deformation history    

Autogenous healing mechanism of cement-based materials

《结构与土木工程前沿(英文)》   页码 948-963 doi: 10.1007/s11709-023-0960-3

摘要: Autogenous self-healing is the innate and fundamental repair capability of cement-based materials for healing cracks. Many researchers have investigated factors that influence autogenous healing. However, systematic research on the autogenous healing mechanism of cement-based materials is lacking. The healing process mainly involves a chemical process, including further hydration of unhydrated cement and carbonation of calcium oxide and calcium hydroxide. Hence, the autogenous healing process is influenced by the material constituents of the cement composite and the ambient environment. In this study, different factors influencing the healing process of cement-based materials were investigated. Scanning electron microscopy and optical microscopy were used to examine the autogenous healing mechanism, and the maximum healing capacity was assessed. Furthermore, detailed theoretical analysis and quantitative detection of autogenous healing were conducted. This study provides a valuable reference for developing an improved healing technique for cement-based composites.

关键词: autogenous healing     cement-based materials     healing mechanism     aggregation effect    

Optimal design of a linkage–cam mechanism-based redundantly actuated parallel manipulator

《机械工程前沿(英文)》 2021年 第16卷 第3期   页码 451-467 doi: 10.1007/s11465-021-0634-6

摘要: A redundantly actuated parallel manipulator (RAPM) with mixed translational and rotational degrees of freedom (DOFs) is challenged for its dimensionally homogeneous Jacobian modeling and optimal design of architecture. In this paper, a means to achieve redundant actuation by adding kinematic constraints is introduced, which reduces the DOFs of the end-effector (EE). A generic dimensionally homogeneous Jacobian is developed for this type of RAPMs, which maps the generalized velocities of three points on the EE to the joint velocities. A new optimization algorithm derived from this dimensionally homogeneous Jacobian is proposed for the optimal design of this type of RAPMs. As an example, this paper presents a spatial RAPM involving linkages and cam mechanisms. This RAPM has 4 DOFs and 6 translational actuations. The linkage lengths and the position of the universal joints of the RAPM are optimized based on the dimensionally homogeneous Jacobian.

关键词: redundant actuation     parallel manipulator     linkage–cam mechanism     Jacobian     optimal design    

Cryogenic minimum quantity lubrication machining: from mechanism to application

《机械工程前沿(英文)》 2021年 第16卷 第4期   页码 649-697 doi: 10.1007/s11465-021-0654-2

摘要: Cutting fluid plays a cooling–lubrication role in the cutting of metal materials. However, the substantial usage of cutting fluid in traditional flood machining seriously pollutes the environment and threatens the health of workers. Environmental machining technologies, such as dry cutting, minimum quantity lubrication (MQL), and cryogenic cooling technology, have been used as substitute for flood machining. However, the insufficient cooling capacity of MQL with normal-temperature compressed gas and the lack of lubricating performance of cryogenic cooling technology limit their industrial application. The technical bottleneck of mechanical–thermal damage of difficult-to-cut materials in aerospace and other fields can be solved by combining cryogenic medium and MQL. The latest progress of cryogenic minimum quantity lubrication (CMQL) technology is reviewed in this paper, and the key scientific issues in the research achievements of CMQL are clarified. First, the application forms and process characteristics of CMQL devices in turning, milling, and grinding are systematically summarized from traditional settings to innovative design. Second, the cooling–lubrication mechanism of CMQL and its influence mechanism on material hardness, cutting force, tool wear, and workpiece surface quality in cutting are extensively revealed. The effects of CMQL are systematically analyzed based on its mechanism and application form. Results show that the application effect of CMQL is better than that of cryogenic technology or MQL alone. Finally, the prospect, which provides basis and support for engineering application and development of CMQL technology, is introduced considering the limitations of CMQL.

关键词: cryogenic minimum quantity lubrication (CMQL)     cryogenic medium     processing mode     device application     mechanism     application effect    

标题 作者 时间 类型 操作

Insight into the promotion mechanism of activated carbon on the monolithic honeycomb red mud catalyst

期刊论文

Efficient promotion of methane hydrate formation and elimination of foam generation using fluorinated

Quan CAO, Dongyan XU, Huanfei XU, Shengjun LUO, Rongbo GUO

期刊论文

并行推进、融合发展——新一代智能制造技术路线

古依莎娜,董景辰,臧冀原,杨晓迎

期刊论文

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

期刊论文

奉献清洁电力,推进能源革命

顾大钊

期刊论文

Air pollutant control and strategy in coal-fired power industry for promotion of China’s emission reduction

Weiliang WANG, Bo LI, Xuan YAO, Junfu LYU, Weidou NI

期刊论文

Health: a dream from reality to the future

null

期刊论文

Promotion of transition metal oxides on the NH

Weiman Li, Haidi Liu, Yunfa Chen

期刊论文

创新的不可预见性及其引发的思考

杨显万,高筱梅

期刊论文

船舶配套业发展研究

汤敏,邱晓峰,胡发国,陈琛

期刊论文

Theory and method of mechanism system design

Huijun ZOU, Qinghua LIANG, Qing ZHANG

期刊论文

Formation mechanism and modeling of surface waviness in incremental sheet forming

期刊论文

Autogenous healing mechanism of cement-based materials

期刊论文

Optimal design of a linkage–cam mechanism-based redundantly actuated parallel manipulator

期刊论文

Cryogenic minimum quantity lubrication machining: from mechanism to application

期刊论文